Abstract

A general method to study classical scattering in n-dimension is developed. Through classical trajectory calculations, the three-body recombination is computed as a function of the collision energy for helium atoms, as an example. Quantum calculations are also performed for the J(Pi) = 0(+) symmetry of the three-body recombination rate in order to compare with the classical results, yielding good agreement for E greater than or similar to 1 K. The classical threshold law is derived and numerically confirmed for the Newtonian three-body recombination rate. Finally, a relationship is found between the quantum and classical three-body hard hypersphere elastic cross sections which is analogous to the well-known shadow scattering in two-body collisions. (C) 2014 AIP Publishing LLC.

Publication Details
Publication Type
Journal Article
Year of Publication
2014
Volume
140
DOI
10.1063/1.4861851
Journal
Journal of Chemical Physics
Contributors
Groups