Abstract

Using first-principles calculations, we identify magic wavelengths lambda(magic) for the 2s-2p and 2s-3p transitions in lithium. The ns and np atomic levels have the same ac Stark shifts at the corresponding magic wavelength, which facilitates state-insensitive optical cooling and trapping. Tune-out wavelengths for which the ground-state frequency-dependent polarizability vanishes are also calculated. Differences of these wavelengths between Li-6 and Li-7 are reported. Our approach uses high-precision, relativistic all-order methods in which all single, double, and partial triple excitations of the Dirac-Fock wave functions are included to all orders of perturbation theory. Recommended values are provided for a large number of Li electric-dipolematrix elements. Static polarizabilities for the 2s, 2p, 3s, 3p, and 3d levels are compared with other theory and experiment where available. Uncertainties of all recommended values are estimated. The magic wavelengths for the uv 2s-3p transition are of particular interest for the production of a quantum gas of lithium [Duarte et al., Phys. Rev. A 84, 061406(R) (2011)].

Publication Details
Publication Type
Journal Article
Year of Publication
2012
Volume
86
DOI
10.1103/PhysRevA.86.042505
Journal
Physical Review A
Contributors