Abstract

We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of long-range forces before they ultimately encounter one another, followed by a probability for the reaction to occur once they do. In this way, the electric-field dependence should be readily parametrized in terms of a pair of fitting parameters (along with a C-6 coefficient) for each asymptotic value of partial-wave quantum numbers vertical bar L, M-L >. From this, the electric-field dependence of the collision rates follows automatically. We present examples for reactive species, such as KRb, and nonreactive species, such as RbCs.

Publication Details
Publication Type
Journal Article
Year of Publication
2010
Volume
82
DOI
10.1103/PhysRevA.82.020703
Journal
Physical Review A
Contributors