We show theoretically that interaction effects in a double-well optical lattice can induce condensates in an excited band. For a symmetric double-well lattice, bosons condense into the bottom of the excited band at the edge of the Brillouin zone if the chemical potential is above a critical value. For an asymmetric lattice, a condensate with zero momentum is automatically induced in the excited band by the condensate in the lowest band. This is due to a combined effect of interaction and lattice potential, which reduces the band gap and breaks the inversion symmetry. Our work can be generalized to a superlattice composed of multiple-well potentials at each lattice site, where condensates can be induced in even higher bands.